Classification and Properties of Matter In chemistry and physics, …. Recommended Videos Problem 2. Problem 3. Problem 4. Problem 5. Problem 6. Problem 7. Problem 8. Problem 9. Problem Video Transcript when talking about Lewis structures, we must understand that they're not truly how electrons look. Numerade Educator. Intro To Chem - Introduction Chemistry is the science of matter, especially its chemical reactions, but a…. Classification and Properties of Matter In chemistry and physics, matter is any substance that has mass and takes up….
Is it possible to isolate one resonance struc…. Explain …. Do resonance structures always contribute equally to the overall structure o…. Do resonance structures always contribute equally to the overall structure…. Explain the concept of resonance. Explain your a….
Explain how it is possible to avoid the concept of resonance by using molecu…. Andrea H. Chemistry 1 month ago. View Full Video Already have an account? Cameron O.
Answer Is it possible to "trap" a resonance structure of a compound for study? Discussion You must be signed in to discuss. Video Transcript when talking about Lewis structures, we must understand that they're not truly how electrons look. Upgrade today to get a personal Numerade Expert Educator answer! Ask unlimited questions. Test yourself. Join Study Groups. Create your own study plan. Join live cram sessions. Live student success coach. Top Chemistry Educators Stephanie C.
University of Central Florida. Nadia L. Rice University. As we said above, full octets are best. However, when dealing with a resonance structure where there absolutely must be an atom with less than a full octet, then follow these principles :.
This becomes particularly important once you start learning about reactions of pi bonds. For now, that does it for a summary of the important themes in resonance. Next stop after a post about some common mistakes will be to apply these principles to chemical reactivity. You should also include a collection of Common Resonance Errors like trying to draw a pi-bond to pi-bond arrow for an allylic anion, etc.
Maybe I missed it in earlier blogs, but what exactly is resonance? Do you think of it as superposition, where several different structures exist at the same instant? If so, then you cannot think of any of your structures as single molecules. But if you think in terms of single molecules, then only one of these structures can exist at any instant. Then the molecule resonates between these structures, but this is not superposition?
To me, resonance represents all the possible structures that can simultaneously exist for a single particle, but at any instant the molecule can have only one structure. That is, superposition is different from resonance. But then, again, I am a physical chemist. Thanks Bryan — resonance structures are a kind of kludge, which have been developed due to the limitations of our system of chemical formulae and formal charge in accurately depicting electron densities.
The very first diagram above shows some curved arrow formalism with a reference to Wikipedia. Might I suggest that a slightly more consistent approach is to start arrows not so much at charges, but at the associated lone pair also shown in your diagram. One can locate the centroids of electron pairs , and therefore in principle one can define coordinates for the start of an arrow and also by the same principle, coordinates for the destination of the arrow.
I have touched upon this theme here where you might want to contemplate the arrows for the reverse of the three reactions shown. Also here. Thanks for the input Henry. It is indeed more consistent to show arrows starting at lone pairs instead of charges. There are costs and benefits to each approach. The benefit of drawing all the lone pairs in is that there is no ambiguity about the location of the electrons and it is more proper to do so.
There is, however, a cost both in the extra clutter of the drawings and also in the extra time involved in drawing in these lone pairs. I choose to do this as well. So long as this caveat is understood i.
However it is not without regret that some information content is lost. Fixed the diagram. Thanks for the correction. Thanks James.
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